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Lionel Messi scored and missed a penalty in Argentina's 3-1 win in an international friendly in Germany on Wednesday night.
Belgium stunned the Netherlands 4-2.
With 2014 World Cup qualifying games approaching fast in September, France drew 0-0 with Uruguay and Fabio Capello's first game in charge of Russia ended in a 1-1 draw with Ivory Coast.
World and European champion Spain beat Puerto Rico 2-1 and England beat Italy by the same scoreline.
Brazil forgot their Olympic final loss with a 3-0 win in Sweden and Portugal beat Panama 2-0 with Cristiano Ronaldo bagging a fine second.
African champions Zambia lost 2-1 to South Korea and China drew 1-1 with Ghana.